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91.
Using reanalysis data and snow cover data derived from satellite observations, respective influences of Indian Ocean Dipole (IOD) and El Niño/Southern Oscillation (ENSO) on the Tibetan snow cover in early winter are investigated. It is found that the snow cover shows a significant positive partial correlation with IOD. In the pure positive IOD years with no co-occurrences of El Niño, negative geopotential height anomalies north of India are associated with warm and humid southwesterlies to enter the plateau from the Bay of Bengal after rounding cyclonically and supply more moisture. This leads to more precipitation, more snow cover, and resultant lower surface temperature over the plateau. These negative geopotential height anomalies north of India are related to the equivalent barotropic stationary Rossby waves in the South Asian wave guide. The waves can be generated by the IOD-related convection anomalies over the western/central Indian Ocean. In contrast, in the pure El Niño years with no co-occurrences of the positive IOD, the anomalies of moisture supply and surface temperature over the plateau are insignificant, suggesting negligible influences of ENSO on the early winter Tibetan snow cover. Further analyses show that ENSO is irrelevant to the spring/early summer Tibetan snow cover either, whereas the IOD-induced snow cover anomalies can persist long from the early winter to the subsequent early summer.  相似文献   
92.
The synthesis of organic molecules via chemical reactions within impact vapor plumes has been proposed as a mechanism to supply organics on a planet. However, the kinetics of chemical reactions within a rapidly expanding vapor plume or quenching process of the reactions has not been studied extensively. In this study, we constructed a new numerical model that calculates kinetics of the entire chemical reactions within an impact vapor plume. Numerical results revealed that the semi-analytical models proposed so far, in which the final amount of a chemical species was given by the equilibrium abundance at the quenching temperature of the fastest reaction path involving the species, underestimates the yield of organic molecules, such as HCN, by up to a factor of 10. This is because the previously used assumption that a species can achieve equilibrium with the rest of the reaction system via the fastest reaction path involving the species is not necessarily valid. Our analysis of the high-temperature H/C/N/O reaction system suggests that the quenching of slow reactions divides the reaction network into smaller reaction sub-systems isolated from the rest of the reaction system. Then, the fastest reaction path cannot equilibrate an isolated reaction sub-system with the rest of the reaction system. Simulation of this actual disequilibrium mechanism requires a simultaneous numerical calculation of the entire reaction network, which is equivalent to conducting a full kinetic model calculation, such as our model. Our numerical code makes it possible to discuss quantitatively the impact chemistry for various situations, such as the Galilean satellites. In this study, our numerical model is applied to the delivery of organic molecules via cometary impact on the Galilean satellites. Our numerical results indicate that small-particle impacts would produce HCN efficiently. Resulting HCN may freeze out immediately and be deposited on satellite surfaces, where it may be eventually converted into complex organics via irradiation of charged particle. On the other hand, large-size impacts may form transient CH4-N2 atmospheres, in which complex organics (tholin) may be formed via energy deposition of UV and/or charged particle. Resulting complex organics may subsequently precipitate on the satellite surfaces without clear correlation with the locations of impact craters. Such distribution of complex organics created by chemical reactions within vapor plumes due to cometary impacts may explain an absorption (4.57 μm) on Galilean satellites nonassociated with observable (moderate- and large-size) impact craters.  相似文献   
93.
One of the key components controlling the chemical composition and climatology of Titan's atmosphere is the removal of reactive atomic hydrogen from the atmosphere. A proposed process of the removal of atomic hydrogen is the heterogeneous reaction with organic aerosol. In this study, we investigate the effect of heterogeneous reactions in Titan's atmospheric chemistry using new measurements of the heterogeneous reaction rate [Sekine, Y., Imanaka, H., Matsui, T., Khare, B.N., Bakes, E.L.O., McKay, C.P., Sugita, S., 2008. Icarus 194, 186-200] in a one-dimensional photochemical model. Our results indicate that 60-75% of the atomic hydrogen in the stratosphere and mesosphere are consumed by the heterogeneous reactions. This result implies that the heterogeneous reactions on the aerosol surface may predominantly remove atomic hydrogen in Titan's stratosphere and mesosphere. The results of our calculation also indicate that a low concentration of atomic hydrogen enhances the concentrations of unsaturated complex organics, such as C4H2 and phenyl radical, by more than two orders in magnitude around 400 km in altitude. Such an increase in unsaturated species may induce efficient haze production in Titan's mesosphere and upper stratosphere. These results imply a positive feedback mechanism in haze production in Titan's atmosphere. The increase in haze production would affect the chemical composition of the atmosphere, which might induce further haze production. Such a positive feedback could tend to dampen the loss and supply cycles of CH4 due to an episodic CH4 release into Titan's atmosphere.  相似文献   
94.
Two OBS arrays were deployed in the southern Okinawa Trough.Some of the OBS records revealedmany earthquakes with intensive T waves but ambiguous body waves.A new method using T waves for epicenter locating was developed that was found to be as precise as the body wave method for locatingepicenters when T waves are clearly recorded.  相似文献   
95.
Based on fault maps, whether or not the fracture geometry of rocks is self-similar, was examined by using a box-counting algorithm. The statistical self-similarity (fractal structure) of the fault fracture systems holds well at the scale of about 2 to 20 km. The fractal dimension in Japan varied from 1.05 to 1.60. The fractal dimension is about 1.5–1.6 at the central part of the Japan Arc, and decreases with distance from the center. At a smaller scale, the fractal structure also holds well in the rock fracture geometry. The fractal dimension of the North Izu Peninsula fault system (branching faults) is 1.49 at the scale of 0.625 to 10 km, the fractal dimension of rock fracture geometry at the scale order of 10–1 to 10–2 meters is about 1.49–1.61. The upper limit of the fractal dimension of rock fracture geometry is about 1.6, judging from the estimation of fractal dimension on actual fracture geometry of rocks. This value may impose a restraint on modeling of faulting and the fracture process of rocks.  相似文献   
96.
The Tsenkher structure, in the Gobi-Altai region of Mongolia, was studied using a wide array of remote sensing data and field observations. The structure has a shallow, 3.6 km wide, central depression bordered by a near-circular ridge (putative crater rim) with breaches to the northwest. The central depression is obliterated partially by fluvial infill through these breaches. Outside the ridge, the western side is a rugged terrain, but the eastern half is characterized by a concentric outer ridge that occurs at about one radius distance from the inner ridge. Although intrusion, salt tectonics and maar crater hypotheses cannot be completely ruled out, its morphology strongly implies an impact origin for the Tsenkher structure. If of impact origin, it has a well-preserved morphology and its position in the basin fills indicates that the formation may have occurred relatively recently, sometime during the late Tertiary or Quaternary. The outer ridge morphology is similar to rampart craters on Mars, whose formation has been attributed to fluidization of a water-rich target layer and ejecta materials, or to atmospheric entrainment and deposition of ejected materials. However, other hypotheses including erosional remnant of ejecta blanket, erosional scarp of structural rim uplift, multi-ring or deeply eroded crater rim of a peak-ring crater are also possible at this stage. A complex fluvial and probable lacustrine history is envisaged within the Tsenkher structure. The structure is also associated with archaeology, including Paleolithic and Bronze Age remains.  相似文献   
97.
Improvement in modern water resource management has become increasingly reliant on better characterizing of the spatial variability of groundwater recharge mechanisms. Due to the flexibility and reliability of GIS-based index models, they have become an alternative for mapping and interpreting recharge systems. For this reason, an index model by integrating water balance parameters (surface runoff, actual evapotranspiration, and percolation) calculated by Thornthwaite and Mather’s method, with maps of soil texture, land cover, and terrain slope, was developed for a sustainable use of the groundwater resources. The Serra de Santa Helena Environmental Protection Area, next to the urbanized area of Sete Lagoas (MG), Brazil, was selected as the study area. Rapid economic growth has led to the subsequent expansion of the nearby urban area. Large variability in soil type, land use, and slope in this region resulted in spatially complex relationships between recharge areas. Due to these conditions, the study area was divided into four zones, according to the amount of recharge: high (>?100 mm/year), moderate (50–100 mm/year), low (25–50 mm/year), and incipient (>?25 mm/year). The technique proved to be a viable method to estimate the spatial variability of recharge, especially in areas with little to no in situ data. The success of the tool indicates it can be used for a variety of groundwater resource management applications.  相似文献   
98.
Molecular weight and trace metal distributions of fulvic and humic acid fractions of marine sediments from the Seto Inland Sea were investigated by using a gel filtration technique in combination with atomic absorption and emission spectrometries. A binary molecular weight distribution was found both in the fulvic acid fraction and in the humic acid fraction. The fulvic acid fractions with molecular weights of less than 1.5×103 and of 5×103?104 accounted for 38–57 % and 25–41 % of the total fulvic acids, respectively, and the humic acid fractions with molecular weights of 102?104 and of over 2×105 accounted for 58–73 % and 16–27 % of the total humic acids, respectively. The components with molecular weights of over 1.5×103 contained 54 %, on average, of the Fe, Zn and Cu in the fulvic acid fraction, and the components with molecular weights of over 104 contained 58 %, on average, of these metals in the humic acid fraction.  相似文献   
99.
The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO2 content (pCO2) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO2 condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO2 through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates.  相似文献   
100.
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